Optical waveguide writing in photochromic material: Photoinduced optical properties by femtosecond laser pulses
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We report on the interaction of high repetition rate (MHz) Ti: sapphire laser pulses with a spiropyran polymer (MIC1). Such a polymer is photochromic, wich has potential applications in integrated optical devices. A thin film of polymer deposited on a glass substrate is irradiated with ultrashort pulses (66 fs) from a Ti: sapphire laser. We demonstrate that it is possible to induce an absorption band in the visible by the use of femtosecond pulses via a two-photon excitation process; this might be useful to accomplish waveguide-like structures formation with photochromic response. © 2011 Copyright Society of Photo-Optical Instrumentation Engineers (SPIE).
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hybrid device; integrated optic; Photochromism; two-photon absorption Glass substrates; High repetition rate; Hybrid devices; Integrated optical devices; Photo-chromic materials; Photo-induced; Potential applications; Spiropyrans; Ti: Sapphire laser; Two-photon absorptions; Two-photon excitations; Chromogenics; Electromagnetic pulse; Integrated optics; Light; Photochromism; Polymers; Solid state lasers; Substrates; Two photon processes; Ultrafast lasers; Ultrashort pulses
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