Document
type: Class

Tetrahedron Letters
publication venue for: Thermolysis of 2-azido-3-(R-anilino)-1,4-naphthoquinones. Nitrene insertion versus hydrogen abstraction
type: Generically Dependent Continuant
type: Information Content Entity
type: Entity
type: Journal
type: Continuant
type: Collection
type: Periodical
type: Document
type: Thing

Continuant
type: Class

Entity
type: Class

Generically Dependent Continuant
type: Class

RDF description of Thermolysis of 2-azido-3-(R-anilino)-1,4-naphthoquinones. Nitrene insertion versus hydrogen abstraction - http://orbis.uaslp.mx/vivo/individual/scopus6516
rights: termsOfUse
date: 2026-08-27T13:00:34
publisher: vivo
type: Document

Consejo Nacional de Ciencia y Tecnologí­a, CONACYT: 155678
type: Relationship
type: BFO_0000020
type: Entity
type: Thing
type: Grant
type: Continuant
funding vehicle for: Thermolysis of 2-azido-3-(R-anilino)-1,4-naphthoquinones. Nitrene insertion versus hydrogen abstraction

Article
type: Class

Information Content Entity
type: Class

Thermolysis of 2-azido-3-(R-anilino)-1,4-naphthoquinones. Nitrene insertion versus hydrogen abstraction
volume: 61
crisid: 6517
origen: scopus
related by: authorship_42590
has funding vehicle: Consejo Nacional de Ciencia y Tecnologí­a, CONACYT: 155678
type: Generically Dependent Continuant
related by: authorship_42593
artnum: 151731
type: Continuant
related by: authorship_42592
most specific type: Article
related by: authorship_42594
most specific type: Document
type: Article
type: Information Content Entity
freetext keyword: 2-azido-3-(R-anilino)-1; 4-naphthoquinones; Hydrogen abstraction; Insertion; Nitrene; Thermolysis 1,4 naphthoquinone derivative; 2 azido 3 (anilino) 1,4 naphthoquinone; unclassified drug; Article; carbon nuclear magnetic resonance; chemical structure; lysis; mass spectrometry; proton nuclear magnetic resonance; structure analysis; thermolysis; ultraviolet visible spectroscopy
type: Thing
estado: published
type: Document
has publication venue: Tetrahedron Letters
abstract: 2-chloro-3-(R-anilino)-1,4-naphthoquinones react with sodium azide upon refluxing in DMF. The thermochemistry of 2-azido-3-(R-anilino)-1,4-naphthoquinone is strongly modified by the substituent on aniline. Having an strong electron-donor like O-R results in the generation of a phenazine while having an electron-withdrawing substituent results in the formation of 2-amino-3-(R-anilino)-1,4-naphthoquinone. The products obtained are explained in terms of singlet and/or triplet nitrene chemistry. © 2020 Elsevier Ltd
type: Entity
e iscopus: 2-s2.0-85080061636
doi: 10.1016/j.tetlet.2020.151731
issue: 14
date time value: article date 6517
related by: authorship_42591