Document
type: Class

Polymer statistics. V. Simulation of polyelectrolytes adsorbed on negative surface
type: Document
has publication venue: Physica A: Statistical Mechanics and its Applications
type: Entity
type: Information Content Entity
type: Generically Dependent Continuant
most specific type: Document
related by: authorship 1548
page start: 53
abstract: We study the geometrical properties of negative-charged linear polyelectrolytes adsorbed on a negative surface (NONS) by using the recently developed simulation method based on the cluster variation method (CVM). This new method has the advantage of the analytical calculation which is based on the equilibrium conditions. At the same time, we can get geometrical information that pure analytical calculations cannot give. Using our simulation method, we find that short chains are preferentially adsorbed, and that the average length of the adsorbed chain is smaller than the average in the solution. The NONS has long tails extending into the solution and a very small area touching the surface. We report the molecular weight (i.e. the length) dependence of the end-to-end distance, the distribution of those which are adsorbed, the layer thickness, the fractions of train, tail and loop, and the average number of tails. The results of this simulation show good qualitative agreement with recent experiments on the adsorption of polyelectrolytes on negative-charged mica surfaces. © 1993.
origen: scopus
type: Thing
date time value: article date 370
crisid: 370
related by: authorship 1549
doi: 10.1016/0378-4371(93)90253-Z
type: Article
most specific type: Article
estado: published
issue: 1-2
has funding vehicle: Consejo Nacional de Ciencia y Tecnología, CONACYT
volume: 195
e iscopus: 2-s2.0-0000833930
type: Continuant
page end: 73

Continuant
type: Class

Entity
type: Class

Physica A: Statistical Mechanics and its Applications
type: Thing
type: Continuant
type: Entity
type: Journal
type: Collection
publication venue for: Polymer statistics. V. Simulation of polyelectrolytes adsorbed on negative surface
type: Generically Dependent Continuant
type: Information Content Entity
type: Periodical
type: Document

Generically Dependent Continuant
type: Class

RDF description of Polymer statistics. V. Simulation of polyelectrolytes adsorbed on negative surface - http://orbis.uaslp.mx/vivo/individual/scopus369
rights: termsOfUse
date: 2026-08-25T06:58:14
publisher: vivo
type: Document

Article
type: Class

Consejo Nacional de Ciencia y Tecnología, CONACYT
type: Relationship
type: BFO_0000020
type: Entity
type: Thing
type: Grant
type: Continuant
funding vehicle for: Polymer statistics. V. Simulation of polyelectrolytes adsorbed on negative surface

Information Content Entity
type: Class