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Crystal structures of 2-formyl-6-methyl- and 6-bromo-2-formylpyridine 4-phenylthiosemicarbazones
Crystal packings; Methylpyridine; Phenyl moieties; Terminal-nitrogen; Thiosemicarbazones; Water molecule; Hydrates; Phenols; Molecules
New thiosemicarbazones-2-formyl-6-methylpyridine 4-phenylthiosemicarbazone (I) and 6-bromo-2-formylpyridine 4-phenylthiosemicarbazone hydrate (II)-were synthesized and their structures were determined. Molecules I and II are nonplanar, the phenyl moiety at the terminal nitrogen atom being rotated by 19.9° and 39.5°, respectively. The water molecule is the main factor determining the crystal packing of molecules II. © Pleiades Publishing, Inc., 2011.
Generically Dependent Continuant
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