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scopus1732
related by: authorship_10363
volume: 52
estado: published
label: Crystal structures of bis-ligand complexes of copper(II) with 2-[(2-hydroxyethylamino)-methyl]-4,6-dinitrophenol, 2,4-dichloro-6-[(2- hydroxyethylamino)-methyl]phenol, and 2,4-dibromo-6-[(2-hydroxyethylamino)- methyl]phenol
origen: scopus
type: Document
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crisid: 1733
related by: authorship_10364
related by: authorship_10365
most specific type: Article
abstract: The crystal structures of bis{2,4-dibromo-6-[(2-hydroxyethylamino)-methyl] phenolato}copper (I), bis{2,4-dichloro-6-[(2-hydroxyethylamino)-methyl] phenolato}copper (II), and bis{2-[(2-hydroxyethylamino)-methyl]-4,6- dinitrophenolato}copper (III) in which the metal atom is located at the center of symmetry are determined using X-ray diffraction. Crystals of compounds I and II are isostructural. The copper atom in the structures of compounds I and I coordinates two singly deprotonated bidentate molecules of the ligand through the phenol oxygen atoms and the azomethine nitrogen atoms with the formation of a distorted planar square. In the crystals, complexes I and II form one-dimensional infinite chains along the b axis. In the structure of compound III, the coordination polyhedron of the central atom is an elongated tetragonal bipyramid with the base formed by the azomethine nitrogen atoms and the phenol oxygen atoms. Both vertices of the bipyramid are occupied by the oxygen atoms of the amino alcohol groups of the neighboring complexes, which are related to the initial complex through the center of symmetry. In turn, the oxygen atoms of the alcohol groups of the initial complex are located at the vertices of the coordination bipyramids of the metal atoms of the neighboring centrosymmetric complexes, thus forming infinite polymer chains along the a axis. © Nauka/Interperiodica 2007.
type: Thing
date time value: article date 1733
freetext keyword: Complexation; Crystal structure; Oxygen; Phenols; Positive ions; Azomethines; Centrosymmetric complexes; Coordination polyhedrons; One dimensional infinite chains; Copper
doi: 10.1134/S1063774507010117
type: Article
related by: authorship_10360
related by: authorship_10361
page end: 107
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page start: 102
most specific type: Document
issue: 1
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e iscopus: 2-s2.0-33846701734
has publication venue: Crystallography Reports
type: Generically Dependent Continuant
related by: authorship_10362

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date: 2026-08-27T12:37:51
publisher: vivo
type: Document
label: RDF description of Crystal structures of bis-ligand complexes of copper(II) with 2-[(2-hydroxyethylamino)-methyl]-4,6-dinitrophenol, 2,4-dichloro-6-[(2- hydroxyethylamino)-methyl]phenol, and 2,4-dibromo-6-[(2-hydroxyethylamino)- methyl]phenol - http://orbis.uaslp.mx/vivo/individual/scopus1732

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Crystallography Reports
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