A bentonitic clay assisted method for the preparation of 2-(R-anilino)-1, 4-naphthoquinones
Conference Paper
-
- Overview
-
- Research
-
- Identity
-
- Additional Document Info
-
- View All
-
Overview
abstract
-
A new and efficient protocol to prepare 2-(R-anilino)-1,4-naphthoquinones in quantitative yields is presented. This synthesis occurs under mild conditions by reacting the corresponding aniline and 1,4-naphthoquinone in the presence of a bentonitic clay. The role of the clay is explained in terms of a reaction mechanism in which an activated complex is formed by the reaction of 1,4-naphthoquinone with Lewis acid sites of the clay. Based on the chemical composition of the clay, with Fe3%2b sites, the last step of the mechanism is proposed to involve an oxidationreduction reaction. © Springer Science%2bBusiness Media, LLC 2008.
publication date
funding provided via
published in
Research
keywords
-
2-Anilino-1,4-naphthoquinone; Acidic clay; Bentonitic clay; Brönsted acid; Fe+3; Lewis acid 1 ,4-Naphthoquinone; 2-Anilino-1,4-naphthoquinone; Activated complex; Chemical compositions; Lewis Acid; Lewis acid site; Oxidation-reduction reaction; Quantitative yields; Reaction mechanism; Synthesis (chemical); Ketones
Identity
Digital Object Identifier (DOI)
Additional Document Info
start page
end page
volume
issue