Stabilization of β-carotene embedded in a silica matrix and study of its physical properties
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This work reports on the behavior of β-carotene within a silica matrix prepared by the sol-gel method. Results show that highly pure β-carotene integrates with the silica to form a silica-based composite. The interaction exhibited between the inorganic matrix and the β-carotene results in a π-d conjugated system that guarantees the development of the protective mechanism of the β-carotene and stabilizes the organic molecule, allowing its preservation at high calcination temperature. The spectroscopic analysis, made through fluorescence emission and infrared spectroscopy, shows the presence of β-carotene within the silica matrix after the composite was calcined at 1000 °C. Furthermore, the structural interactions of the β-carotene with the silica and the protective function of the β-carotene change the crystallization route naturally followed by the silica when exposed to increasing temperature. In this case, the amorphous silica matrix is preserved after high-temperature calcination, which is beneficial for biomedical applications as it allows the release and transport of the β-carotene to take full advantage of its health benefits. © 2020 The Author(s). Published by IOP Publishing Ltd.
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Amorphous silica; Fluorescence spectroscopy; Rietveld refinement; ß-carotene stabilization Calcination; Fluorescence; Fluorescence spectroscopy; High temperature applications; Infrared spectroscopy; Medical applications; Rietveld refinement; Sol-gel process; Sol-gels; Spectroscopic analysis; Stabilization; After high temperature; Amorphous silica; Amorphous Silica matrix; Biomedical applications; Calcination temperature; Fluorescence emission; Increasing temperatures; Structural interactions; Silica
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