Light absorption properties of mesoporous barium hexaferrite, BaFe12O19

Light absorption properties are one of the most important characteristics of semiconductor materials, since it is related to particle size, electric resistance, powder density, and dielectric constant. Barium hexaferrite (BaFe12O19) particles were synthesized by ceramic and chemical co-precipitation method. Light absorption properties were studied in relation to the particle size, morphology, and surface porosity. The band gap was calculated by the Kubelka-Munk method from the obtained experimental absorption spectrum. Band gap energies of 1.82 and 1.86 eV were estimated for the particles synthesized by the ceramic method and for the co-precipitation method respectively. The results show that both synthesized BaFe12O19 samples can be effectively excited with visible light irradiation. In addition to this, due to its other good characteristics such as its magnetic properties, high resistance to corrosion, and chemical stability, make the barium hexaferrite an excellent material for diverse technological applications. © 2019 Elsevier B.V.

Bandgap; Barium hexaferrite; Kubelka-Munk method Absorption spectroscopy; Barium; Barium compounds; Ceramic materials; Chemical stability; Coprecipitation; Corrosion resistance; Dielectric materials; Energy gap; Ferrite; Iron compounds; Light; Morphology; Particle size; Semiconductor materials; Absorption property; Barium hexaferrites; Chemical coprecipitation method; Coprecipitation method; Kubelka-munk methods; Surface porosity; Technological applications; Visible-light irradiation; Light absorption

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