Zinc oxide decorated multi-walled carbon nanotubes: Their bolometric properties
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We report the synthesis of MWNT/ZnO hybrid nanostructures. A simple, affordable, chemical procedure to functionalize MWNTs with ZnO nanoparticles was performed. A significant portion of the surface of MWNTs was covered with ZnO nanoparticles; these particles formed highly porous spherical nodules of 50-150 nm in diameter, sizes that are an order of magnitude larger than similar ZnO nanonodules reported in the literature. Hence, the self-assembled nanocomposite the ZnO exhibited a large surface-to-volume ratio, which is a very advantageous property for potential catalytic applications. The resultant MWNT/ZnO nanocomposites were characterized by x-ray diffraction, scanning and high-resolution transmission electron microscopy, and UV-vis and Raman spectroscopy. The temperature coefficient of resistance (TCR) of the nanocomposites was measured and reported. The average TCR value goes from -5.6%25/K up to -18%25/K, over temperature change intervals from 10 K to 1 K. Based on these TCR results, the nanocomposite MWNT/ZnO prepared in this work is a promising material, with potential application as a bolometric sensor. © 2018 IOP Publishing Ltd.
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bolometers; multiwalled carbon nanotubes; nanocomposite; zinc oxide Bolometers; Carbon; Carbon nanotubes; High resolution transmission electron microscopy; Metal nanoparticles; Nanocomposites; Nanoparticles; Nanostructures; Nanotubes; Scanning electron microscopy; Temperature; X ray diffraction; Yarn; Zinc; Zinc compounds; Zinc oxide; Bolometric properties; Catalytic applications; Chemical procedures; Hybrid nanostructures; Porous spherical; Temperature changes; Temperature coefficient of resistance; ZnO nanoparticles; Multiwalled carbon nanotubes (MWCN)
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