Effect of frothers and dodecylamine on bubble size and gas holdup in a downflow column

Bubble size and gas holdup were characterized in a two phase gas-water system in a laboratory downflow column. The effect of the cationic surfactant dodecyl amine (MW 185, HLB 10.7) and the frothers MIBC (MW 102, HLB 6.05) and polyglycol F507 (MW 425, HLB 8.63) on the bubble size and gas holdup were investigated. In addition, the effect of blends of MIBC-dodecyl amine (DDA) and F507-DDA on these parameters was assessed. The bubble Critical Coalescence Concentration (CCC) followed the order MIBC > DDA > F507. When blending the frothers with DDA at a concentration below its CCC, the frother CCC decreased and bubbles of finer size were obtained below and above the frother CCC. Static surface tension measurements of aqueous solutions with frothers and DDA as well as with frothers-DDA blends show coadsorption of DDA at the air/aqueous solution interface. The surface tension of aqueous solutions prepared with the blends decreased with the addition of DDA and varied linearly with the frother concentration within the concentration range studied. The gas holdup in the downflow column was determined by the bubble size and decreased with the bubble size. It is shown that frother-DDA blends gave the lowest gas holdup in the downflow column. This work is relevant for the reverse flotation of quartz from iron ores using amine collectors in cells with downflow systems. © 2015 Elsevier Ltd. All rights reserved.

Amine collector; Bubble columns; Bubble size; Flotation; Frothers Blending; Bubble columns; Cationic surfactants; Dyes; Flotation; Froth flotation; Gases; Ionization of gases; Iron ores; Ore treatment; Solutions; Surface tension; Bubble size; Concentration ranges; Critical coalescence concentration; Dodecyl amines; Frothers; Reverse flotation; Solution interface; Surface tension measurements; Phase interfaces

VIVO