Interfacial insertion of a poly(3,4-ethylenedioxythiophene): Poly(styrenesulfonate) layer between the poly(3-hexyl thiophene) semiconductor and cross-linked poly(vinyl alcohol) insulator layer in organic field-effect transistors
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The role of a thin layer of conductive poly(3,4-ethylenedioxythiophene) doped with polystyrene sulfonate (PEDOT: PSS), inserted between the gate dielectric and the active layer in poly(3-hexylthiophene)-based transistors was investigated. The devices were fabricated in the bottom-gate top-contact geometry by using cross-linked poly(vinyl alcohol) as the dielectric, whereas the PEDOT: PSS layer was prepared by using an aged aqueous dispersion with addition of different amounts of dimethyl sulfoxide (DMSO) as a secondary dopant. Under these conditions, both a significant reduction in the number of electrically active traps at the interface with the semiconductor and an improvement in the field-effect mobility were obtained, whereas the low power consumption was preserved. The threshold voltage was also displaced by approximately -1 V. © 2014 IOP Publishing Ltd.
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aged PEDOT: PSS dispersion; interface; organic field-effect transistor; P3HT-based transistors; poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate); secondary doping Dimethyl sulfoxide (DMSO); Electrically actives; Field-effect mobilities; Low-power consumption; Poly (3-hexylthiophene); Poly(3 ,4ethylenedioxythiophene): poly(styrenesulfonate); Poly-3 ,4-ethylenedioxythiophene; Polystyrene sulfonate; Dimethyl sulfoxide; Dispersions; Gate dielectrics; Interfaces (materials); Organic field effect transistors; Organic solvents; Polyvinyl alcohols; Semiconductor doping; Transistors; Conducting polymers
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