abstract

• In this study, synchrotron radiation x-ray absorption spectroscopy was used to characterize natural volcanic ash from Mount Cameroon. The latter was employed to remove Fe3 ions from aqueous solutions, as an option for its application in water treatment. The electronic properties and local structure of Fe adsorbed on the volcanic ash were investigated. The results show that the raw volcanic ashes and those used to adsorb Fe3 are principally composed of magnetite, Fe(II) sulphate, hematite, and Fe(II) oxide. The volcanic ash materials contain Fe ions coordinated by oxygen atoms with Fe–O bond length provided by magnetite, Fe(II) sulphate, hematite, and Fe(II) oxide. Two types of interactions were suggested: one between oxygen and Fe photo-absorber in the first shell, and the second between another atom of Fe and photo-absorber in the second coordination shell. The adsorption mechanism for Fe3 removal was attributed to the ion exchange and/or chemisorption processes. © 2021 Elsevier B.V.
• In this study, synchrotron radiation x-ray absorption spectroscopy was used to characterize natural volcanic ash from Mount Cameroon. The latter was employed to remove Fe3%2b ions from aqueous solutions, as an option for its application in water treatment. The electronic properties and local structure of Fe adsorbed on the volcanic ash were investigated. The results show that the raw volcanic ashes and those used to adsorb Fe3%2b are principally composed of magnetite, Fe(II) sulphate, hematite, and Fe(II) oxide. The volcanic ash materials contain Fe ions coordinated by oxygen atoms with Fe–O bond length provided by magnetite, Fe(II) sulphate, hematite, and Fe(II) oxide. Two types of interactions were suggested: one between oxygen and Fe photo-absorber in the first shell, and the second between another atom of Fe and photo-absorber in the second coordination shell. The adsorption mechanism for Fe3%2b removal was attributed to the ion exchange and/or chemisorption processes. © 2021 Elsevier B.V.

authors

• Carranza Álvarez Candy
• Labrada-Delgado G.
• Loredo-Portales R.

publication date

• 2021-01-01

funding provided via

• The World Academy of Sciences, TWAS; Elettra-Sincrotrone Trieste; Abdus Salam International Centre for Theoretical Physics, ICTP; The World Academy of Sciences, TWAS: 3240294919; Consejo Nacional de Ciencia y Tecnología, CONACYT: 20180368, CB2018/286990, PN-2018/3947; Universidad Autónoma de San Luis Potosí, UASLP  Grant

published in

• Physica B: Condensed Matter  Journal

keywords

• Adsorption mechanism; Electronic properties; Iron removal; Synchrotron radiation; Volcanic ash; X-ray absorption spectroscopy

Digital Object Identifier (DOI)

• 10.1016/j.physb.2021.413128

PubMed ID

start page

end page

volume

• 617

issue