Nonlinear effects in the electrophoresis of a spherical colloidal particle
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The reduced electrophoretic mobility-reduced zeta potential relationship for a charged macroparticle is shown to be nonuniversal and to be highly nonlinear. In agreement with experimental results, a mobility reversal due to the macroion’s charge inversion and a nonlinear dependence of the mobility on salt concentration is obtained. © 1999 The American Physical Society.
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