abstract

• 2-(Thiocyanomethylthio)-benzothiazole (TCMTB) is used as fungicide in the paper, tannery, paint, and coatings industries, and its study is important as it is considered toxic to aquatic life. In this study, a comparison of direct anodic oxidation (AO) using a borondoped diamond electrode (BDD) and electro-Fenton (EF) processes for TCMTB degradation in acidic chloride and sulfate media using a FM01-LC reactor was performed. The results of the electrolysis processes studied in the FM01-LC reactor showed a higher degradation of TCMTB with the anodic oxidation process than with the electro-Fenton process, reaching 81%25 degradation for the former process versus 47%25 degradation for the latter process. This difference was attributed to the decrease in H2O2 during the EF process, due to parallel oxidation of chlorides. The degradation rate and current efficiency increased as a function of volumetric flow rate, indicating that convection promotes anodic oxidation and electro-Fenton processes. The results showed that both AO and EF processes could be useful strategies for TCMTB toxicity reduction in wastewaters. Copyright © 2018 Armando Vázquez et al.

authors

• Alvarado L.
• Cruz Gaona Roel
• Lazaro Báez María Isabel
• Nava J.L.
• Rodríguez Torres Israel
• Vázquez A.

publication date

• 2018-01-01

funding provided via

• Consejo Nacional de Ciencia y Tecnología, CONACYT: 240522  Grant

published in

• International Journal of Photoenergy  Journal

Digital Object Identifier (DOI)

• 10.1155/2018/5290975

start page

end page

volume

• 2018