Raman spectroscopy mapping of Si (001) surface strain induced by Ni patterned micro arrays
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Patterned arrays of nickel microstructures were fabricated by electron beam lithography and DC sputtering on the surface of Si (001) substrates. Influence of the micro-arrays on the Si substrate surface was evaluated using polarized micro-Raman spectroscopy. Raman spectra maps were taken in two configurations z(xx)z and z(yy)z for arrays of 18.5 μm × 15.5 μm. The Si longitudinal optical (LO) phonon shifted to lower vibrational frequencies by 5 cm-1 in regions near to the vicinities of the Ni micro structures. From the deformation elastic theory, it is found that this frequency shift is explained by an in-plane tensile stress induced by the Ni micro arrays producing a strain of 1.4%25. © 2017 Author(s).
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Electron beam lithography; Lithography; Microstructure; Nickel; Raman spectroscopy; Substrates; DC sputtering; Elastic theory; Frequency shift; Longitudinal optical phonons; Patterned arrays; Polarized micro-Raman; Si (001) substrate; Si(001) surfaces; Silicon
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