Aziridine nitrogen inversion by dynamic NMR: Activation parameters in a fused bicyclic structure
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The nitrogen inversion of a N-phenyl aziridine fused to a succinimide ring is influenced by the presence of a phenyl ring in the succinimide moiety. The endo invertomer is favored, showing an unsymmetrical equilibrium in variable 1H NMR studies. © 2013 American Chemical Society.
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Activation parameter; Aziridines; Bicyclic structure; Dynamic NMR; Nitrogen inversion; NMR studies; Phenyl rings; Succinimide; Chemistry; Organic compounds; Nitrogen; aziridine derivative; nitrogen; succinimide; article; chemical structure; conformational transition; density functional theory; enthalpy; entropy; proton nuclear magnetic resonance; synthesis
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