Photodegradation of indigo carmine and methylene blue dyes in aqueous solution by SiC-TiO 2 catalysts prepared by sol-gel
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Indigo carmine and methylene blue dyes in aqueous solution were photodegraded using SiC-TiO 2 catalysts prepared by sol-gel method. After thermal treatment at 450°C, SiC-TiO 2 catalysts prepared in this work showed the presence of SiC and TiO 2 anatase phase. Those compounds showed specific surface area values around 22-25m 2g -1, and energy band gap values close to 3.05eV. In comparison with TiO 2 (P25), SiC-TiO 2 catalysts showed the highest activity for indigo carmine and methylene blue degradation, but this activity cannot be attributed to the properties above mentioned. Therefore, photocatalytic performance is due to the synergy effect between SiC and TiO 2 particles caused by the sol-gel method used to prepare the SiC-TiO 2 catalysts. TiO 2 nanoparticles are well dispersed onto SiC surface allowing the transfer of electronic charges between SiC and TiO 2 semiconductors, which avoid the fast recombination of the electron-hole pair during the photocatalytic process. © 2012 Elsevier B.V..
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Indigo carmine; Methylene blue; Photodegradation; SiC-TiO 2; Sol-gel Anatase phase; Electron hole pairs; Electronic charges; Energy bandgaps; Indigo Carmine; Methylene Blue; Methylene blue dye; Photocatalytic performance; Photocatalytic process; SiC-TiO 2; Synergy effect; TiO; Well-dispersed; Aromatic compounds; Catalyst activity; Photodegradation; Silicon carbide; Sol-gel process; Sol-gels; Solutions; Titanium dioxide; indigo carmine; methylene blue; silicon carbide; titanium dioxide; anatase; aqueous solution; dye; electrical conductivity; gel; heating; photodegradation; reaction kinetics; silicon; temperature profile; aqueous solution; article; catalyst; chemical analysis; dispersion; electron; photodegradation; semiconductor; Carbon Compounds, Inorganic; Catalysis; Indigo Carmine; Methylene Blue; Microscopy, Electron, Scanning; Photochemical Processes; Silicon Compounds; Solutions; Titanium; Water; X-Ray Diffraction
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