A nuclear export sequence in GPN-loop GTPase 1, an essential protein for nuclear targeting of RNA polymerase II, is necessary and sufficient for nuclear export
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XAB1/Gpn1 is a GTPase that associates with RNA polymerase II (RNAPII) in a GTP-dependent manner. Although XAB1/Gpn1 is essential for nuclear accumulation of RNAPII, the underlying mechanism is not known. A XAB1/Gpn1-EYFP fluorescent protein, like endogenous XAB1/Gpn1, localized to the cytoplasm but it rapidly accumulated in the cell nucleus in the presence of leptomycin B, a chemical inhibitor of the nuclear transport receptor Crm1. Crm1 recognizes short peptides in substrate proteins called nuclear export sequences (NES). Here, we employed site-directed mutagenesis and fluorescence microscopy to assess the functionality of all six putative NESs in XAB1/Gpn1. Mutating five of the six putative NESs did not alter the cytoplasmic localization of XAB1/Gpn1-EYFP. However, a V302A/L304A double mutant XAB1/Gpn1-EYFP protein was clearly accumulated in the cell nucleus, indicating the disruption of a functional NES. This functional XAB1/Gpn1 NES displays all features present in most common and potent NESs, including, in addition to Φ1-Φ4, a critical fifth hydrophobic amino acid Φ0. Therefore, in human Gpn1 this NES spans amino acids 292-LERLRKDMGSVAL-304. XAB1/Gpn1 NES is remarkably conserved during evolution. XAB1/Gpn1 NES was sufficient for nuclear export activity, as it caused a complete exclusion of EYFP from the cell nucleus. Molecular modeling of XAB1/Gpn1 provided a mechanistic reason for NES selection, as functionality correlated with accessibility, and it also suggested a mechanism for NES inhibition by intramolecular masking. In conclusion, we have identified a highly active, evolutionarily conserved NES in XAB1/Gpn1 that is critical for nucleo-cytoplasmic shuttling and steady-state cytoplasmic localization of XAB1/Gpn1. © 2012 Elsevier B.V.
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GPN-loop GTPase 1 (Gpn1); Nuclear export sequence; Nucleocytoplasmic transport; RNA polymerase II nuclear targeting; XAB1 amino acid; gpn1 enzyme; guanosine triphosphatase; RNA polymerase II; unclassified drug; xab1 enzyme; article; cell nucleus; cytoplasm; enzyme activity; enzyme inhibition; enzyme localization; fluorescence microscopy; human; hydrophobicity; nuclear export signal; nuclear localization signal; priority journal; sequence analysis; site directed mutagenesis; Active Transport, Cell Nucleus; Amino Acid Sequence; Cell Nucleus; Conserved Sequence; Evolution, Molecular; Genes, Reporter; GTP-Binding Proteins; HEK293 Cells; Humans; Hydrophobic and Hydrophilic Interactions; Models, Molecular; Molecular Sequence Data; Nuclear Export Signals; Protein Structure, Secondary; Recombinant Fusion Proteins; RNA Polymerase II; Structure-Activity Relationship
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