Spontaneous two-dimensional spherical colloidal structures
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Two-dimensional spherical crystalline colloidal structures are formed at the interface between water and oil as the result of spontaneous emulsification and colloidal self-assembly. When water droplets are introduced in oil containing a lipophilic surfactant, smaller water droplets of uniform size are spontaneously produced at the spherical interface. Initially of submicrometer size, the small droplets at the interface self-assemble, forming ordered structures, and grow uniformly with time until they reach a size of a few micrometers, maintaining the crystalline structure. © 2007 American Chemical Society.
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Colloids; Crystal structure; Emulsification; Interfaces (materials); Self assembly; Surface active agents; Spherical interfaces; Spontaneous emulsification; Water droplets; Crystalline materials
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