abstract

• The importance of the textural and physicochemical characteristics upon the adsorption capacity of the commercial activated carbons (ACs) Coconut, Wood, Merck, Darco, and Norit towards ronidazole (RNZ) and diclofenac (DCF) from water solution was investigated thoroughly in this work. At pH = 7, Coconut AC and Wood AC presented the highest adsorption capacity towards RNZ (444 mg/g) and DCF (405 mg/g). The maximum mass of RNZ adsorbed onto Coconut AC was higher in this study than those outlined previously in other works. Besides, the maximum capacity of Wood AC for adsorbing DCF was comparable to those found for other ACs. The adsorption capacity of all the ACs was increased by surface area and was favored by incrementing the acidic site concentration. The π-π stacking interactions were the predominant adsorption mechanism for the RNZ and DCF adsorption on ACs, and the acidic sites favored the adsorption capacity by activating the π-π stacking. Electrostatic interactions did not influence the adsorption of RNZ on Coconut AC, but electrostatic repulsion decreased that of DCF on Wood AC. The adsorption of DCF on Wood AC was reversible but not that of RNZ on Coconut AC. Besides, the adsorption of RNZ and DCF on the Coconut and Wood ACs was endothermic in the range of 15–25 °C. © 2022, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.

authors

• Carrales-Alvarado D.H.
• Díaz Flores Paola Elizabeth
• Leyva Ramos Roberto
• Mendoza Mendoza Esmeralda
• Moral-Rodríguez A.I.

publication date

• 2022-01-01

funding provided via

• Consejo Nacional de Ciencia y Tecnología, CONACYT: 864; Universidad Autónoma de San Luis Potosí, UASLP: C20-FAI-10–27.27  Grant

published in

• Environmental Science and Pollution Research  Journal

keywords

• Activated carbon; Adsorption mechanism; Diclofenac; Ronidazole; Surface chemistry

Digital Object Identifier (DOI)

• 10.1007/s11356-021-17466-7

PubMed ID

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